Fluoride Action Network

Equilibrium sorption of fluoride on the activated alumina in aqueous solution.

Source: Desalination and Water Treatment 197:224-236. | Authors: Rakesh Kumar and Prabhakar Sharma.
Posted on September 23rd, 2020
Location: International
Industry type: Water Treatment

Removal of fluoride is a desalination technology in which fluoride ions from aqueous solution are adsorbed on suitable adsorbent surfaces. In this study, adsorption potential was performed on both activated alumina (AA) and grinded activated alumina (GAA) by batch experiments for different contact time, pH, fluoride concentration, and adsorbent dose. Results indicated that adsorption occurred rapidly in the beginning, and equilibrium adsorption capacity was achieved as 23.73 and 28 mg g-1 (i.e., mg of fluoride per g of alumina) in case of AA, whereas it was noted as 26.33 and 39 mg g-1 for GAA for pH of 3.0 and fixed fluoride concentration of 75 and 100 mg L-1 , respectively in aqueous solution. Furthermore, adsorption isotherms were performed using three isotherm models in which the Freundlich model indicated a better fit (in the order of Freundlich > Langmuir > Dubinin-Radushkevich), showing heterogeneous nonlinear monolayer sorption. Consequently, pseudo-kinetics for fluoride adsorption on alumina particles for second-order (R 2 > 0.98) had better fit over the pseudo-first-order kinetic adsorption of fluoride. The exo-thermic behavior (?H° =-58.78 J mol-1) at solid-liquid interface delivered a decrease in fluoride adsorption with an increase in temperature of GAA. It has been noted that the adsorption of fluoride reduced in the presence of co-existing ions on AA and GAA, as the sorption capacity on adsorbent found in the order of CO 3 2-> PO 4 3-> SO 4 2-> NO 3-> Cl-. Results also revealed that the GAA could be a prospective adsorbent which can be regenerated as well as reused for the removal of fluoride ions from contaminated water.

*Original abstract online at https://www.researchgate.net/publication/344043525_Equilibrium_sorption_of_fluoride_on_the_activated_alumina_in_aqueous_solution